[2,2′-Imino­diethano­lato(2−)-κ3 O,N,O′][4-(meth­oxy­carbonyl­meth­yl)phen­yl]boron

نویسندگان

  • Ahmed L. Zein
  • Louise N. Dawe
  • Paris E. Georghiou
چکیده

The title compound, C(13)H(18)BNO(4), was readily obtained from the reaction of methyl 4-boronobenzene acetate with ethano-lamine. A combination of inter-molecular N-H⋯O hydrogen bonds and C-H⋯π inter-actions leads to the pairwise association of mol-ecules.

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Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ3 O,O′:O;κ3 O:O,O′-bis­[(2,2′-bipyridine-κ2 N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ2 O,O′)cadmium(II)]

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The title complex, [Nd(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN or [Nd(altpy)(dbm)(NO(3))(2)]·CH(3)CN (altpy = 4'-all-yl-oxy-2,2':6',2''-terpyridine, dbm = dibenzoyl-methanide anion), has been synthesized from 4'-all-yloxy-2,2':6',2''-terpyridine, dibenzoyl-methanate and neodymium nitrate. The Nd(3+) atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms...

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Bis{μ-2-[3-carboxyl­atometh­yl-4-(phenyl­sulfan­yl)phen­yl]propano­ato-κ4 O,O′:O′′,O′′′}bis­[(2,2′-bipyridine-κ2 N,N′)cadmium]

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Bis(μ-pyridine-2,5-dicarboxyl­ato)-κ3 N,O 2:O 5;κ3 O 5:N,O 2-bis­[aqua­(2,2′-bipyridine-κ2 N,N′)cobalt(II)] dihydrate

In the centrosymmetric title compound, [Co(2)(C(7)H(3)NO(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, the two Co(II) cations are bridged by pairs of pyridine-2,5-dicarboxyl-ate anions across an inversion center. Besides two pyridine-2,5-dicarboxyl-ate anions, one bidentate 2,2'-bipyridine and one water mol-ecule coordinate to the Co cation, completing a distorted octa-hedral coordination geometr...

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010